Alkmaar, who led the standings with a seven goal advantage on goal difference, suffered a setback after 19 minutes against Excelsior when Boy Waterman was sent off after conceding a penalty that was converted by Luigi Bruins.
Three minutes later midfielder Simon Cziommer gave Alkmaar some hope with an equalizer but Henrico Drost restored the lead for the home side after 59 minutes.
With 19 minutes left Danny Koevermans levelled the match but in injury time Johan Voskamp sealed victory for Excelsior who also finished with 10 men after Rene van Dieren was sent off.
Urby Emanuelson and Klaas-Jan Huntelaar struck either side of the break to hand Ajax a 2-0 win at Willem II Tilburg. However, they could not add to their score and missed out on the title by a whisker.
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