"It's not a bad draw. Of course I hope Brazil will play with us when it already has 6 points. Then we have a big chance of advancing into the next round with them," Dujkovic said.
Dujkovic added China would not be giving up when it plays against Brazil.
"Though Brazil is hot favorite of the group and is also the title favorite, I still hope we can make some trouble. We are playing at home and though we respect Brazil we will not give up."
Dujkovic tipped South Korea to be China's rival in the quarterfinals, saying the host's Asian neighbor is likely to top Group D.
"I think Korea has the best chance as the group winner. And Cameroon and Italy will fight for second place.
"But first of all we have to pay attention to ourselves. We must play our best football and advance from the group."
Reigning champion Argentina, presumably led by established superstars such as Juan Roman Riquelme and Lionel Messi, is in Group A with Cote d'Ivoire, Australia and Serbia.
For the Netherlands, emphatic winner of the UEFA U-21 Championship, it will be a first Olympic appearance in 55 years.
The Dutch are in Group B and face opponents US, Nigeria and Japan.
Women aim to bounce back
China's women's team also has good reason to be happy as its group E avoids the major title contenders and sees itself joined by Sweden, Canada and Argentina.
None of these three teams advanced into last year's World Cup second round and China is likely to beat at least two of them on home soil.
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