Carlos Tevez cut inside from the right and the ball was laid into the path of Rodriguez by Jonas Gutierrez.
The midfielder applied a simple finish to slide the ball in from close range, prompting Maradona, his arms still folded as he protected himself from the cold, to stand up briefly in celebration.
Scotland's Lee Miller (R) clashes with Argentina's Martin Demichelis during their their international friendly soccer match at Hampden Park stadium in Glasgow, Scotland November 19, 2008.
The home side, who had struggled to cope with Argentina's pace, came back into the game before half-time. James McFadden came close twice for the Scots with one shot deflected over by Martin Demichelis and the other saved well by goalkeeper Juan Pablo Carrizo.
Scotland almost gifted their visitors a second goal early after the restart when Paul Hartley conceded possession deep inside his own half and Rodriguez fed Ezequiel Lavezzi, who fired over.
Lee Miller, brought on for Chris Iwelumo at the break, was soon knocking down a Kris Commons free-kick which Carrizo saved bravely at the feet of advancing McFadden in the 55th minute.
Substitute David Clarkson almost gave Scotland an equalizer one minute from time when he ran through the defence on the right but was thwarted by a last ditch tackle.
Maradona took over from resigned Alfio Basile two weeks ago after Argentina lost their World Cup qualifier 1-0 away to Chile last month.
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