Turkey began the second period looking to kill off the game, but once again Nihat was unable to find the target.
Those wasted chances proved to be expensive for the home side as Spain drew level from the penalty spot.
A clear handball was punished by Xabi Alonso who slotted the ball home from 11 yards.
The game looked to be heading for a draw, but in injury time, substitute Dani Guiza found space on the left touchline and crossed for Riera to score from close range.
The win leaves Spain six points clear at the top of their group and it would take a disaster to stop them qualifying for the World Cup finals in South Africa.
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