There is a tight race for fourth place in the table between Villarreal, Valencia and Atletico Madrid. Five points separate the three sides that have a chance of making the last Champions Leaguespot.
Villarreal has a difficult game at home to seventh placed Malaga and Manuel Preciado's team needs to recover from a 1-1 Champions League draw against Arsenal.
Valencia travels to play Sporting Gijon with striker David Villa making an emotional return to the club where he began his career. Meanwhile an irregular Atletico Madrid visits Deportivo laCoruna.
The week also sees drama at the bottom of the Primera Liga. Second from bottom Numancia entertains bottom side Espanyol in a match that is make or break for both teams' hopes of avoiding relegation.
Osasuna and Athletic Bilbao can both take a huge step towards safety in the Reino de Navarra stadium, while new Betis coach Jose Nogues makes his debut away to Racing Santander.
Finally Mallorca plays away to Almeria.
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