Darya Shytko of Ukraine scored 502.7 points, edging three-time world champion Sonja Pfeilschifter and Beate Gauss. The German duo took home silver and bronze.
Boasting the same 399 points in the qualifying round, the trio staged a fierce competition in Saturday's final.
Shytko staged a come-from-behind drama despite a poor shot of 9.7 points in her fourth try, and she successfully surpassed left-handed Pfeilschifter in the ninth shot with 492.0 points against 491.7 points.
During the breath-taking final shot, Shytko tallied an amazing 10.7 points, while Pfeilschifter, who was the last to trigger, ended up with 10.6 points, a handsome score but shy of winning the gold.
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