Neither driver has been confirmed although on Sunday Mercedes Sports boss Norbert Haug revealed he was attempting to secure Heidfeld, who has driven for BMW since 2006.
Since clinching the title in Brazil last month Button has been in protracted contract negotiations with Brawn, the 29-year-old reportedly turning down a four million pound offer.
That represents one million rise on his 2009 salary after he took a five million pound pay cut when Ross Brawn took over from Honda.
As part of Monday's deal Daimler AG has given up its 40 percent stake in McLaren but Mercedes will continue to supply engines to the team for the next six seasons.
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