Messi again in the 69th minute, who conceded a free-kick but Tzorvas pulled off a great save.
Argentina finally found the net at the 77th minute when Demichelis, who came from Bayern Munich, hit a left-foot shot into the net. The goal put Argentina's coach Diego Maradona into exhilaration.
Messi hit a shot on the post at the 86th minute. The talisman came back again at the 89th minute when his shot was blocked by Tzorvas. Substitute Martin Palermo easily put the ball into the far corner of the net.
Argentina made to the last 16 with three brilliant victories, joined by South Korea, who drew Nigeria 2-2. And Greece and Nigeria were out.
Martin Demichelis of Argentina (R) vies with Georgios Samaras of Greece during their 2010 World Cup Group B soccer match in Polokwane, South Africa, June 22, 2010. Argentina won 2-0 and qualifies for the next round
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