Technicians will debug the cardinals' lodgings and mobile phones will be banned altogether during the conclave.
Britain's formerly most senior Roman Catholic cleric, Cardinal Keith O'Brien, has said he will not take part in the conclave after standing down amid allegations of improper behaviour.
On Sunday, he admitted his sexual conduct had at times "fallen beneath the standards expected of me".
He apologised and asked forgiveness from those whom he had "offended".
Cardinal O'Brien resigned as Archbishop of St Andrews and Edinburgh last Monday after three priests and a former priest made allegations against him dating back to the 1980s.
Benedict, 85, officially ceased to be the Pope at 20:00 local time (19:00 GMT) on Friday.
He left the Vatican in a motorcade before being flown by helicopter to the papal retreat at Castel Gandolfo, near Rome.
He has vowed "unconditional obedience and reverence" to his successor.
The German pontiff, who was born Joseph Ratzinger, will continue to be known as Benedict XVI, with the new title of "pope emeritus".
The theologian is expected to retire to a monastery on a hill inside Vatican City. Officials say he will not be able to intervene publicly in the next papacy although he may offer advice.
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