The visitors could have reaped a higher victory but Bayern custodian Neuer denied Ronaldo as well as Benzema in the closing period with superb safes.
With the result, Real Madrid are in sight of their seventh straight semi-final, and they ended Bayern's 16-game winning streak on home soil.
"We played a very good first half. The second half is difficult to judge. We have to accept the defeat. Our first half performance gives us confidence for the second leg. We still have 90 minutes to play," Bayern coach Carlo Ancelotti said.
Bayern Munich will have to turn around the 2-1 loss at Real in the second leg on Tuesday.
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