Christian Streich's men threw everything up front but it wasn't enough as Nils Petersen rattled only the woodwork in the closing period.
"Owing the second half we can speak of a deserved victory but that is only a first step. Next week we have a difficult game at Augsburg," Mainz' sporting director Rouven Schroeder said.
With the result, Mainz snapped their six-game winless run to move on the 15th place and out of the drop zone whereas Freiburg slipped on the 16th position and into the relegation battle.
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