Waldo scored a 20th minute goal to take Valladolid to fourth from bottom and at the same time confirm Rayo Vallecano's relegation to the second division.
Rayo lost 4-1 away to Valladolid on Saturday as their defensive woes came back to haunt them again.
Jose Campana and Ruben Vezo put Levante 2-0 up by halftime and although Alvaro gave Rayo hope with a goal 20 minutes from time Levante sealed the win with late goals from Jason and Enis Bardhi as Rayo hurled players looking for an equalizer.
Huesca also saw their relegation confirmed on Sunday as they capitulated 6-2 at home to Valencia.
The game was over by halftime as Valencia led 5-0 with a goal from Daniel Wass after two minutes. Rodrigo Moreno scored in the 16th minute and Santi Mina netted after 20 and 32 minutes before Xabi Etxeita scored an own goal.
Rodrigo scored his second of the night seven minutes after halftime before Gonzalo Melero scored a 66th minute consolation for the home side and Alexandre Gallar netted a 92nd minute penalty.
Borja Iglesias scored twice as Espanyol defeated Atletico Madrid 3-0 to keep their hopes of playing in Europe next season alive.
Real Sociedad can still play in Europe next season after Manu Garcia's 24th minute own goal gave them a 1-0 win away to Alaves in the Basque derby.
The win takes Real Sociedad up to eighth in the table, while Alaves drop to 10th on the same number of points.
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