Boca captain Pablo Perez was one of the worst-affected players and was taken to hospital in an ambulance after being struck in the eye with shards of broken glass.
Others that needed medical attention were Sebastian Villa, Julio Buffarini and Augustin Almendra, according to local news reports.
Boca and River drew 2-2 in the first leg at Boca's La Bombonera earlier this month.
It is the first time that Argentina's famous rivals have met in the final of South America's premier club competition.
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