Santi Mina's sixth goal of the season nine minutes later leveled the scores, but although Goncalo Guedes returned from injury as a substitute for Valencia, Eibar had the best chances in the closing minutes and Joan Jordan scored the winning goal three minutes from the end with a powerful header following Ivi Alejo's fine cross.
Girona's incredible season continued as they defeated Getafe 1-0 to move into contention for a place in Europe thanks to Cristian Stuani's fifth minute goal.
The Catalans' win momentarily lifted them into sixth place in the table, but that only lasted for four hours before Villarreal reclaimed the final European place with a 1-0 win away to Celta Vigo.
Both sides were missing key players, but Celta suffered without Spain international Iago Aspas and Pablo Fornals' first ever goal for Villarreal was enough to give them all three points.
Espanyol looked to be cruising to an away victory as they led 2-0 away to struggling Las Palmas with just 13 minutes remaining only to allow the home side to draw level through Loric Remi and Calleri and Las Palmas would have won had it not been for Pau Lopez's stunning 96th minute save to deny a Jonathan Viera penalty.
The Basque derby in San Mames between Athletic Club Bilbao and Real Sociedad was less thrilling and ended 0-0 in a match where tension and tackles held the edge over football and the best news from the 0-0 draw between Sevilla and Levante was Eduardo Berizzo's return to the Sevilla dugout just 17 days after a cancer operation.
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