Next up for Peng is Puerto Rican Olympic Gold medalist Monica Puig, who earlier in the day also needed three sets to dispatch her opponent Mona Barthel 6-0, 6-7 (0), 6-4.
The only top-seeded player who managed to avoid embarrassment was 9th-seeded Agnieszka Radwanska, who saw off Slovakian Magdalena Rybarikova, 6-4, 7-5.
Other action saw France's Caroline Garcia recover from a one-set deficit to take out Germany's Angelique Kerber 3-6, 6-3, 6-1. Garcia goes on to meet American Christina McHale in round two.
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