Jakub Vadlejch of Czech Republic finished second in 89.73m ahead of fellow countryman Petr Frydrych with 88.32m.
Rohler, from Germany, made a 88.26m throw in his second attempt and finished fourth while Beijing worlds winner Yego was eliminated after the first three rounds.
In other events, Russia's Maria Lasitskene, competing as the authorized neutral athlete, retained the women's high jump title as the 24-year-old cleared 2.03 meters for the gold medal. Ukraine's Yuliia Levchenko took silver in 2.01 and Poland's Kamila Licwinko was third in 1.99.
Lasitskene, who missed last year's Rio Olympics because of Russia's suspension, failed at 1.99 twice but regained form thereafter.
"My two failed attempts at 1.99m woke me up," she said. "A gold medal here was my main goal for this season but certainly I would like to raise the bar a bit higher. I didn't like any one of my attempts at 2.08m." She challenged 2.08 three times but all failed.
Rio Olympic champions U.S. team regained the women's 4x100m world crown which last won at 2011 Daegu worlds as they sailed to victory in 41.82 seconds while hosts Britain gladly bagged a silver in 42.12. Defending champions Jamaica clocked 42.19 for the bronze.
In the women's 100m hurdles, Sally Pearson, who clinched the world title in 2011 and Olympic gold five years ago, clocked 12.59 seconds to win the first gold and only medal for Australia at the world championships by far. American Dawn Harper Nelson, who won the Olympic gold in Beijing and silver in London behind Pearson, took silver in 12.63. Germany's Pamela Dutkiewicz finished third in 12.72.
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