Villarreal depended on themselves from the start of the day, and after Soldado opened the scoring inside the first minute they rarely looked as if they were going to struggle, despite Nani briefly levelling the scores with a second half header.
Trigueros quickly put Villarreal back in front and with Valencia fans leaving the stands Sansone assured Villarreal's win.
Athletic Club Bilbao were victims of the last ever league game in the Vicente Calderon as they lost 3-1 to Atletico Madrid, who led 2-0 after just 11 minutes thanks to two goals from Fernando Torres.
Inaki Williams gave Athletic, who needed to match Real Sociedad's result to assure a sixth place finish, hope, but Angel Correa finished off a counter-attack to give the Calderon a fitting sendoff.
Real Sociedad knew they had to go one better than Athletic to finish sixth and twice fell behind to Celta Vigo, as the Galician side looked to give coach Eduardo Berizzo a fitting send off.
The game looked to be up for 'La Real' when Andrew Hjulsager put Celta 2-1 up in the 90th minute, but Juanmi's 94th minute header sees Real Sociedad into Europe, while Athletic will still qualify if Barca beat Alaves in next weekend's Cup final.
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