In other matches of the 24-nation round robin tournament, world No. 1 Rafael Nadal and his Spanish counterpart Roberto Bautista Agut were flawless in Perth, beating Uruguay 3-0.
Also having success in Western Australia, Japan defeated Georgia 2-1 in their Group B showdown, while in Brisbane's other contest South Africa demolished Chile 3-0 on the back of some Kevin Anderson brilliance.
Meanwhile, Sydney fans saw Australian Open finalist Marin Cilic lead Croatia to a 2-1 victory over Poland and Dominic Thiem spearhead Austria's 3-0 win over Argentina.
With Australia and Serbia now in the final eight, there are still six places up for grabs in the 15 million U.S. dollar tournament.
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