The title came as the icing on the cake as Peng has inspired the team of Tianjin for the women's team title and secured the mixed doubles gold on Sunday.
The 23-year-old is also in the run for a record four golds at the prestigious meet by reaching the final at the singles event, where Peng will take on Zhejiang's Han Xinyun on Tuesday.
"I haven't thought too much about the singles event," said Peng, "I'm very happy at the moment, and meanwhile very tired. I just want to take a good rest and fight tomorrow.
"Either lose or win, I will be happy, since I have already harvested three gold medals."
In road cycling, veteran cyclist Wong Kam-po sprinted in the end of a 201-kilometer route and brought Hong Kong the first gold medal at the national meet.
It is also Wong's third gold medal in the road cycling event in four National Games.
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