Copenhagen edged ahead in the 26th minute when Martin Vingaard's effort from outside the box found the bottom corner of Alexandros Tzorvas' net.
And they doubled their advantage with former Chelsea and Birmingham midfielder Jesper Gronkjaer firing home from the penalty spot five minutes into the second period before Djibril Cisse's own goal made it 3-0, with Cedric Kante's late consolation meaningless.
Barcelona's much changed side, who were assured of top spot before kick-off, ended Rubin Kazan's hopes of sneaking through with a 2-0 victory at Camp Nou.
Andreu Fontas scored the opening goal when he fired home via the aid of a substantial deflection after good work from Thiago Alcantara.
Arguably the world's best substitute, Lionel Messi, had joined the fray when Victor Vazquez doubled Barca's lead in the 82nd minute.
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