Dani Ceballos, who had entered the game for the injured Casemiro, scored Madrid's fourth goal in injury time and Brais Mendez netted Celta's second in the 94th minute.
Deportivo Alaves are just a point behind Barca after fighting back from a goal down to win 2-1 at home to bottom of the table Huesca.
Moi Gomez opened the scoring in the 36th minute, only for Alaves winger, Jony to bring the home side level five minutes later and a dreadful error from Huesca defender Nelson Semedo opened the door for Ruben Soriano to score the winning goal midway through the second half.
Rayo Vallecano are still without a home win this season despite another entertaining game in their Vallecas Stadium which ended 2-2 against Villarreal as the visitors equalized with just 10 minutes left on the clock.
Saturday saw Atletico Madrid twice come back from behind to claim a 3-2 win at home to Athletic Club Bilbao, who probably deserved more from the game.
Inaki Williams opened the scoring from close range in the first half and then re-established Athletic's lead, shortly after Thomas Partey's thunderbolt had made it 1-1.
Two goals from set pieces; the second in injury time, from Rodrigo and Diego Godin, then turned the game around to give Atletico all three points in the last 10 minutes.
Saturday kicked off with a competitive 0-0 draw between Valladolid and Eibar, who had chances to win, but ended with 10 men after central defender Anaitz Arbilla was sent off for two yellow cards midway through the second half.
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