However, Silvia Dominguez and Torres scored a three-pointer each for 61-59 just two minutes before the buzzer, before Torres scored another field goal and a free-throw to help Spain overtake the lead at 62-61.
Shao Ting then scored key two points to put China back in the lead at 63-62, and an additional free-throw to set the final score.
Li Yueru achieved a double-double with 13 points and 15 rebounds, and Li Meng scored 13 points.
In Spain's ranks, Torrens scored 17 points, followed by 12 points of Nicholls.
Both teams recorded their first victories on Thursday, China against Britain, and Spain against South Korea. On Sunday, China plays against South Korea while Spain meets Britain.
The tournament was moved from Foshan in China to Belgrade, Serbia due to the coronavirus epidemic.
For the Tokyo Olympic Games, 16 women's teams have been divided into four groups with the top three qualifying from each group after a round-robin competition. Enditem
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